Immobilization of polyoxometalates in the Zr-based metal organic framework UiO-67.

نویسندگان

  • William Salomon
  • Catherine Roch-Marchal
  • Pierre Mialane
  • Paul Rouschmeyer
  • Christian Serre
  • Mohamed Haouas
  • Francis Taulelle
  • Shu Yang
  • Laurent Ruhlmann
  • Anne Dolbecq
چکیده

The encapsulation of polyoxometalates within the large pores of the Zr(iv) biphenyldicarboxylate UiO-67 metal-organic framework has been achieved, for the first time, by direct solvothermal synthesis. The resulting POM@UiO-67 composite materials were fully characterized by XRPD, IR, MAS NMR, N2 porosimetry measurements and cyclic voltammetry.

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عنوان ژورنال:
  • Chemical communications

دوره 51 14  شماره 

صفحات  -

تاریخ انتشار 2015